Celebration of Scholars
Quantitation of Metal Ions in Surface Waters
Name:
Leah Hall
Major: Chemistry
Hometown: Hoffman Estates, IL
Faculty Sponsor:
Christine Blaine
Other Sponsors:
Type of research: SURE
Funding: Noyce Grant, Sure
Abstract
The use of common
road salts, NaCl and CaCl2, in the winter results in melting snow
and spring rains washing these ions off impervious pavements into surrounding
surface waters. High concentrations of sodium and chloride ions in these waters
are known to be hazardous to aquatic life.
Since 2007, chloride ion concentrations have been quantified in the Pike
River and more recently in Lake Michigan and the surrounding watershed. Data supports an increase in chloride ion
concentration from fall to spring months.
The purpose of this study was to develop instrumental methods for
quantitation of Na+(aq), Mg2+(aq),
and Ca2+(aq) ions by Microwave Plasma Atomic Emission
Spectrometry (MP-AES). Multiple ion
standard mixtures were analyzed for interferences. From these methods, baseline
metal ion concentrations were measured in the Pike River, Pike Creek and Lake
Michigan. Preliminary data from Pike
River samples collected on 8/8/2017 measured mean concentrations of [Na+]
= 43.7±1.4 ppm, [Mg2+] = 25.9±0.8 ppm and [Ca2+] =
62.6±1.2 ppm. Seasonal monitoring will
determine whether increases in these metal ion concentrations are seen from
road salt runoff into the Pike River Watershed.